If $ ext{Salt A}$ ($ ext{MCl}$) and $ ext{Salt B}$ ($ ext{MF}$) share the same $K_{sp}$, how does their solubility compare in an acidic $ ext{pH}$ environment?

Answer

$ ext{Salt B}$ solubility will be significantly increased, while $ ext{Salt A}$ solubility will be unaffected.

Since $ ext{Cl}^-$ is the conjugate base of a strong acid, it does not react with $ ext{H}^+$. $ ext{F}^-$, being the conjugate base of a weak acid, reacts readily with $ ext{H}^+$, causing the solubility of $ ext{Salt B}$ to increase significantly compared to $ ext{Salt A}$.

If $	ext{Salt A}$ ($	ext{MCl}$) and $	ext{Salt B}$ ($	ext{MF}$) share the same $K_{sp}$, how does their solubility compare in an acidic $	ext{pH}$ environment?
ChemistryacidBasepHsolubility