What key chemical agent did John Herschel discover could 'fix' photographic images?

Answer

Sodium thiosulfate

Herschel discovered that a solution of sodium thiosulfate, which he termed 'hyposulphite of soda,' was effective at stopping the light-sensitive silver salts from darkening further, thus making the image permanent.

What key chemical agent did John Herschel discover could 'fix' photographic images?
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