Why does the bulk material of a doped semiconductor remain electrically neutral overall?

Answer

The stationary, localized charge of the impurity ion balances the mobile charge carrier it creates.

In n-type material, the fixed positive ion balances the mobile electron; in p-type material, the fixed negative ion balances the mobile hole, ensuring zero net charge for the entire crystal.

Why does the bulk material of a doped semiconductor remain electrically neutral overall?

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Doping: The Most Important Part of Making Semiconductors - YouTube

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